Further progress in industrial electrochemical generators' designs utilising SOFC considerably depends on problem of obtaining fuel cell materials with predefined properties [1,2]. Due to this fact, considerable efforts of designers are directed on creation of optimum composition «anode-electrolyte-cathode», and on microconstruction of SOFC materials (selection of phase and element composition, defect structure formation, etc.). In the second problem nanocomposite systems having unique properties are of greatest interest [3]. Utilising of such materials as solid electrolyte may allow significantly improve cell's parameters, in particular, increase ionic conductivity [4,5].However mechanisms leading to this effect were not determined singly. In this article the influence of nanoparticles ensemble with work of exit that different from the rest of the matrixon the change of electron density in SOFC materials have been examined theoretically. The calculations of concentration distribution of free carriers around single particle and for microparticles ensemble were fulfilled. Inconclusion possible directions of forming of nanostructures conformably to SOFC materials discussed.