Authors: Bezverkhniy Volodymyr Dmytrovych, Bezverkhniy Vitaliy Volodymyrovich
The MO method and the VS method are analyzed using the principle of quantum superposition and the method of describing a quantum system consisting of several parts. It is shown that the main assumption of the molecular orbital method (namely, that a molecular orbital can be represented by a linear combination of overlapping atomic orbitals) comes into insurmountable contradiction with the principle of quantum superposition. It is also shown that the description of a quantum system consisting of several parts (accepted in quantum mechanics) actually prohibits assigning corresponding canonical structures to the terms of the equation in the VS method.
Метод МО и метод ВС анализируются с помощью принципа квантовой суперпозиции и метода описания квантовой системы состоящей из нескольких частей. Показано, что основное допущение метода молекулярных орбиталей (а именно то, что молекулярную орбиталь можно представить линейной комбинацией перекрывающихся атомных орбиталей) вступает в непреодолимое противоречие с принципом квантовой суперпозиции. Также показано, что описание квантовой системы состоящей из нескольких частей (принимаемое в квантовой механике) фактически запрещает приписывать в методе ВС членам уравнения соответствующие канонические структуры.
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[v1] 2022-07-04 23:57:55
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