Authors: Bezverkhniy Volodymyr Dmytrovych, Bezverkhniy Vitaliy Volodymyrovich
The theory of hybridization of atomic orbitals by L. Pauling is analyzed using the principle of quantum superposition. It is shown that the principle of quantum superposition, and hence quantum mechanics as a whole, is in an insurmountable contradiction with the theory of hybridization of atomic orbitals. Since the concept of σ- and π-bonds automatically follows from the theory of hybridization, the classical chemical description of single, double and triple bonds (based on σ- and π-bonds) is also in an insurmountable contradiction with the principle of quantum superposition.
Теория гибридизации атомных орбиталей Л. Полинга проанализирована с использованием принципа квантовой суперпозиции. Показано, что принцип квантовой суперпозиции, и следовательно квантовая механика в целом, находятся в непреодолимом противоречии с теорией гибридизации атомных орбиталей. Так как понятие о σ- и π-связях автоматически следует из теории гибридизации, то и классическое химическое описание одинарных, двойных и тройных связей (на основании σ- и π-связей) также находится в непреодолимом противоречии с принципом квантовой суперпозиции.
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