The quantum model of valence electron generation orbital penetration of alkali metal elements with unique stable structure is investigated. The electric field outside the atomic kernel is usually expressed by the Coulomb field of the point charge mode, and the composite electric field in atomic kernel can be equivalent to the electric field inside the sphere with uniform charge distribution or other electric fields without divergence point. The exact solutions of two Schrodinger equations for the bound state of the Coulomb field outside the atom and the binding state of the equivalent field inside the atom determine two different quantization energy formulas respectively. Here we show that the atomic kernel surface is the only common zero potential surface that can be selected. When the orbital penetration occurs, the law of conservation of energy requires that the energy level formulas of the two bound states must have corresponding quantum numbers to make them equal. As a result, there is no solution to the quantum number equation, indicating that the two quantum states of the valence electron are incompatible. This irreconcilable contradiction shows that the quantized energy of quantum mechanics cannot absolutely satisfy the law of conservation of energy.